{"id":41,"date":"2016-02-06T19:33:28","date_gmt":"2016-02-06T14:03:28","guid":{"rendered":"http:\/\/www.chemtopper.com\/myblog\/?page_id=41"},"modified":"2025-07-18T20:31:33","modified_gmt":"2025-07-18T15:01:33","slug":"how-to-draw-lewis-dot-structure","status":"publish","type":"page","link":"https:\/\/www.chemtopper.com\/myblog\/how-to-draw-lewis-dot-structure\/","title":{"rendered":"How to Draw Lewis Dot Structure"},"content":{"rendered":"<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">Understanding the Importance of Lewis Dot Structures<\/span><\/h2>\n<p class=\"\" data-start=\"235\" data-end=\"842\"><span style=\"color: #000000;\">To begin with, <strong data-start=\"250\" data-end=\"273\">Lewis dot structure<\/strong> is a classical bonding model that uses only the <strong data-start=\"322\" data-end=\"343\">valence electrons<\/strong> of atoms. It plays a <strong data-start=\"365\" data-end=\"386\">foundational role<\/strong> in chemistry because it connects to many important concepts. For example, Lewis structures are essential for understanding <strong data-start=\"510\" data-end=\"530\">chemical bonding<\/strong>, <strong data-start=\"532\" data-end=\"545\">resonance<\/strong>, <strong data-start=\"547\" data-end=\"603\">valence shell electron pair repulsion (VSEPR) theory<\/strong>, <strong data-start=\"605\" data-end=\"638\">molecular polarity prediction<\/strong>, and even the <strong data-start=\"653\" data-end=\"689\">mechanisms of chemical reactions<\/strong>. <strong data-start=\"691\" data-end=\"704\">Therefore<\/strong>, it is crucial to learn how to draw Lewis dot structures <strong data-start=\"762\" data-end=\"776\">accurately<\/strong> for atoms, ions, molecules, polyatomic ions, and ionic compounds.<\/span><\/p>\n<h2 data-start=\"235\" data-end=\"842\"><span style=\"color: #000000;\">Learning Lewis Structures Step-by-Step<\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong data-start=\"896\" data-end=\"911\">Fortunately<\/strong>, you can learn to create correct Lewis dot structures by following <strong data-start=\"979\" data-end=\"1000\">four simple steps<\/strong>. These are designed to be <strong data-start=\"1033\" data-end=\"1055\">easy to understand<\/strong> and <strong data-start=\"1060\" data-end=\"1082\">practical to apply<\/strong>. <strong data-start=\"1084\" data-end=\"1095\">However<\/strong>, it is important not to skip or rearrange them, especially during the learning process. <strong data-start=\"1184\" data-end=\"1226\">Each step builds upon the previous one<\/strong>, so completing them in order ensures you fully grasp the method. <strong data-start=\"1292\" data-end=\"1325\">Once you master the technique<\/strong>, you will be able to draw the Lewis structure of <strong data-start=\"1375\" data-end=\"1399\">any chemical species<\/strong> quickly and with confidence.<\/span><\/p>\n<h2 data-start=\"235\" data-end=\"842\"><span style=\"color: #000000;\">Key Concepts to Watch For<\/span><\/h2>\n<p><span style=\"color: #000000;\"><strong data-start=\"1469\" data-end=\"1486\">Along the way<\/strong>, you will encounter important terms such as <strong data-start=\"1531\" data-end=\"1552\">valence electrons<\/strong>, <strong data-start=\"1554\" data-end=\"1575\">electronegativity<\/strong>, <strong data-start=\"1577\" data-end=\"1612\">stable electronic configuration<\/strong>, <strong data-start=\"1614\" data-end=\"1632\">formal charges<\/strong>, <strong data-start=\"1634\" data-end=\"1651\">bonding pairs<\/strong>, <strong data-start=\"1653\" data-end=\"1667\">lone pairs<\/strong>, and the types of bonds\u2014<strong data-start=\"1692\" data-end=\"1702\">single<\/strong>, <strong data-start=\"1704\" data-end=\"1714\">double<\/strong>, and <strong data-start=\"1720\" data-end=\"1736\">triple bonds<\/strong>. <strong data-start=\"1738\" data-end=\"1779\">If you&#8217;re not familiar with these yet<\/strong>, don\u2019t worry. <strong data-start=\"1794\" data-end=\"1833\" data-is-only-node=\"\">Each term will be explained clearly<\/strong> during the steps, so you will understand how and why they matter in the context of Lewis structures.<\/span><\/p>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\"><strong><span style=\"text-decoration: underline;\">STEP 1\u00a0: COUNT THE TOTAL VALENCE ELECTRONS.<\/span><\/strong><\/span><\/h2>\n<p data-start=\"143\" data-end=\"216\"><span style=\"color: #000000;\"><strong>What Are Lewis Dot Structures and Why Do Valence Electrons Matter?<\/strong><\/span><\/p>\n<p class=\"\" data-start=\"218\" data-end=\"511\"><span style=\"color: #000000;\">In a <strong data-start=\"223\" data-end=\"246\">Lewis dot structure<\/strong>, we use <strong data-start=\"255\" data-end=\"285\">only the valence electrons<\/strong> to represent how atoms bond and interact. These are the electrons found in the <strong data-start=\"365\" data-end=\"384\">outermost shell<\/strong> of an atom\u2019s electron configuration, and they play a <strong data-start=\"438\" data-end=\"454\">central role<\/strong> in determining chemical reactivity and bonding behavior.<\/span><\/p>\n<p class=\"\" data-start=\"513\" data-end=\"717\"><span style=\"color: #000000;\"><strong data-start=\"513\" data-end=\"533\">To put it simply<\/strong>, valence electrons are the ones involved in forming chemical bonds\u2014whether ionic or covalent. <strong data-start=\"628\" data-end=\"642\">That\u2019s why<\/strong> understanding their placement is key to drawing accurate Lewis structures.<\/span><\/p>\n<p class=\"\" data-start=\"719\" data-end=\"861\"><span style=\"color: #000000;\"><strong data-start=\"719\" data-end=\"735\">For instance<\/strong>, consider the example below. It will help illustrate how valence electrons are represented and used in a Lewis dot structure.<\/span><\/p>\n<p><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons.jpg\" rel=\"attachment wp-att-161\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-209 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons.jpg\" alt=\"Valence electrons of Nitrogen atom and Chlorine atom \" width=\"799\" height=\"716\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons.jpg 799w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-300x269.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-768x688.jpg 768w\" sizes=\"auto, (max-width: 799px) 100vw, 799px\" \/><\/a><\/span><\/p>\n<h2 data-start=\"141\" data-end=\"202\"><span style=\"color: #000000;\">How to Find Valence Electrons Using the Periodic Table<\/span><\/h2>\n<p class=\"\" data-start=\"204\" data-end=\"398\"><span style=\"color: #000000;\">If you&#8217;re not comfortable writing out full electronic configurations, <strong data-start=\"274\" data-end=\"289\">don\u2019t worry<\/strong>\u2014there\u2019s a much easier way to determine the number of <strong data-start=\"343\" data-end=\"364\">valence electrons<\/strong>: <strong data-start=\"366\" data-end=\"397\">just use the periodic table. In<\/strong>\u00a0most cases, the number of valence electrons is the <strong data-start=\"454\" data-end=\"482\">same as the group number<\/strong> (for main group elements). <strong data-start=\"510\" data-end=\"526\">For example:<\/strong><\/span><\/p>\n<ul data-start=\"528\" data-end=\"801\">\n<li class=\"\" data-start=\"528\" data-end=\"597\">\n<p class=\"\" data-start=\"530\" data-end=\"597\"><span style=\"color: #000000;\"><strong data-start=\"530\" data-end=\"540\">Oxygen<\/strong> is in <strong data-start=\"547\" data-end=\"559\">Group 16<\/strong>, so it has <strong data-start=\"571\" data-end=\"594\">6 valence electrons<\/strong>.<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"598\" data-end=\"669\">\n<p class=\"\" data-start=\"600\" data-end=\"669\"><span style=\"color: #000000;\"><strong data-start=\"600\" data-end=\"613\">Beryllium<\/strong> is in <strong data-start=\"620\" data-end=\"631\">Group 2<\/strong>, so it has <strong data-start=\"643\" data-end=\"666\">2 valence electrons<\/strong>.<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"670\" data-end=\"739\">\n<p class=\"\" data-start=\"672\" data-end=\"739\"><span style=\"color: #000000;\"><strong data-start=\"672\" data-end=\"684\">Nitrogen<\/strong>, found in <strong data-start=\"695\" data-end=\"707\">Group 15<\/strong>, has <strong data-start=\"713\" data-end=\"736\">5 valence electrons<\/strong>.<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"740\" data-end=\"801\">\n<p class=\"\" data-start=\"742\" data-end=\"801\"><span style=\"color: #000000;\"><strong data-start=\"742\" data-end=\"754\">Chlorine<\/strong>, in <strong data-start=\"759\" data-end=\"771\">Group 17<\/strong>, has <strong data-start=\"777\" data-end=\"800\">7 valence electrons<\/strong>.<\/span><\/p>\n<\/li>\n<\/ul>\n<p class=\"\" data-start=\"803\" data-end=\"945\"><span style=\"color: #000000;\"><strong data-start=\"803\" data-end=\"821\">As you can see<\/strong>, this method is quick, reliable, and perfect for building Lewis dot structures without getting into complex configurations.<\/span><\/p>\n<p class=\"\" data-start=\"947\" data-end=\"995\"><span style=\"color: #000000;\"><strong data-start=\"947\" data-end=\"995\">That\u2019s your first step\u2014simple and effective!<\/strong><\/span><\/p>\n<figure id=\"attachment_215\" aria-describedby=\"caption-attachment-215\" style=\"width: 960px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/calculating-valence-electrons-with-the-help-of-the-periodic-table-.jpg\" rel=\"attachment wp-att-215\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-215 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/calculating-valence-electrons-with-the-help-of-the-periodic-table-.jpg\" alt=\"how to draw Lewis Dot Structure-Calculating valence electrons with the help of the periodic table\" width=\"960\" height=\"720\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/calculating-valence-electrons-with-the-help-of-the-periodic-table-.jpg 960w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/calculating-valence-electrons-with-the-help-of-the-periodic-table--300x225.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/calculating-valence-electrons-with-the-help-of-the-periodic-table--768x576.jpg 768w\" sizes=\"auto, (max-width: 960px) 100vw, 960px\" \/><\/a><figcaption id=\"caption-attachment-215\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Calculating valence electrons with the help of the periodic table<\/strong><\/span><\/figcaption><\/figure>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>Lewis dot structure of N atom<\/strong><\/span><\/h2>\n<figure id=\"attachment_205\" aria-describedby=\"caption-attachment-205\" style=\"width: 640px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-N-atom.jpg\" rel=\"attachment wp-att-205\"><img loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-205\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-N-atom-1024x556.jpg\" alt=\"Lewis dot structure of N atom\" width=\"640\" height=\"348\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-N-atom-1024x556.jpg 1024w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-N-atom-300x163.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-N-atom-768x417.jpg 768w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-N-atom.jpg 1057w\" sizes=\"auto, (max-width: 640px) 100vw, 640px\" \/><\/a><figcaption id=\"caption-attachment-205\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of N atom<\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Let\u2019s do one more example:<\/span><\/p>\n<h2><span style=\"color: #000000;\"><strong>Lewis dot structure of Se atom<\/strong><\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>Se atom<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Electronic configuration:<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">[Ar]3d<sup>10<\/sup>4s<sup>2<\/sup>4p<sup>4<\/sup><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Valence shell is 4s<sup>2<\/sup>4p<sup>4\u00a0 <\/sup>with total 6 electrons.<\/span><\/p>\n<figure id=\"attachment_222\" aria-describedby=\"caption-attachment-222\" style=\"width: 640px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Se-atom-.jpg\" rel=\"attachment wp-att-152\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-222 size-large\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Se-atom--1024x630.jpg\" alt=\"lewis dot structure of Se atom\" width=\"640\" height=\"394\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Se-atom--1024x630.jpg 1024w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Se-atom--300x185.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Se-atom--768x472.jpg 768w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Se-atom-.jpg 1185w\" sizes=\"auto, (max-width: 640px) 100vw, 640px\" \/><\/a><figcaption id=\"caption-attachment-222\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of Se atom<\/strong><\/span><\/figcaption><\/figure>\n<h6 style=\"text-align: left;\"><\/h6>\n<figure id=\"attachment_224\" aria-describedby=\"caption-attachment-224\" style=\"width: 794px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Cl-atom-.jpg\" rel=\"attachment wp-att-224\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-224\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Cl-atom-.jpg\" alt=\"Lewis dot structure of Cl atom\" width=\"794\" height=\"520\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Cl-atom-.jpg 794w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Cl-atom--300x196.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Cl-atom--768x503.jpg 768w\" sizes=\"auto, (max-width: 794px) 100vw, 794px\" \/><\/a><figcaption id=\"caption-attachment-224\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of Cl atom<\/strong><\/span><\/figcaption><\/figure>\n<figure id=\"attachment_273\" aria-describedby=\"caption-attachment-273\" style=\"width: 1309px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lewis-dot-structures-of-atoms-PT.jpg\" rel=\"attachment wp-att-225\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-273 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lewis-dot-structures-of-atoms-PT.jpg\" alt=\"Lewis dot structure of all atoms \" width=\"1309\" height=\"940\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lewis-dot-structures-of-atoms-PT.jpg 1309w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lewis-dot-structures-of-atoms-PT-300x215.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lewis-dot-structures-of-atoms-PT-768x552.jpg 768w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lewis-dot-structures-of-atoms-PT-1024x735.jpg 1024w\" sizes=\"auto, (max-width: 1309px) 100vw, 1309px\" \/><\/a><figcaption id=\"caption-attachment-273\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of all atoms of the main periodic table<\/strong><\/span><\/figcaption><\/figure>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">Lewis dot structure of Monoatomic\u00a0 ions:<\/span><\/h2>\n<h3 class=\"\" data-start=\"137\" data-end=\"188\"><span style=\"color: #000000;\">How Charges Affect Valence Electrons in Ions<\/span><\/h3>\n<p class=\"\" data-start=\"190\" data-end=\"377\"><span style=\"color: #000000;\">When atoms become ions, they do so by either <strong data-start=\"235\" data-end=\"266\">gaining or losing electrons<\/strong>. This change directly affects the <strong data-start=\"301\" data-end=\"338\">total number of valence electrons<\/strong> used in their <strong data-start=\"353\" data-end=\"376\">Lewis dot structure<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"379\" data-end=\"431\"><span style=\"color: #000000;\">To understand this better, consider the following:<\/span><\/p>\n<ul data-start=\"432\" data-end=\"654\">\n<li class=\"\" data-start=\"432\" data-end=\"553\">\n<p class=\"\" data-start=\"434\" data-end=\"553\"><span style=\"color: #000000;\">If an ion has a <strong data-start=\"450\" data-end=\"469\">negative charge<\/strong>, it means the atom has <strong data-start=\"493\" data-end=\"513\">gained electrons<\/strong> equal to the magnitude of the charge.<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"554\" data-end=\"654\">\n<p class=\"\" data-start=\"556\" data-end=\"654\"><span style=\"color: #000000;\">On the other hand, if the ion has a <strong data-start=\"592\" data-end=\"611\">positive charge<\/strong>, it means the atom has <strong data-start=\"635\" data-end=\"653\">lost electrons<\/strong>.<\/span><\/p>\n<\/li>\n<\/ul>\n<p class=\"\" data-start=\"656\" data-end=\"822\"><span style=\"color: #000000;\"><strong data-start=\"656\" data-end=\"669\">Therefore<\/strong>, you must <strong data-start=\"680\" data-end=\"709\">add or subtract electrons<\/strong> from the valence electrons of the neutral atom, depending on the charge, <strong data-start=\"783\" data-end=\"793\">before<\/strong> drawing the Lewis structure.<\/span><\/p>\n<p class=\"\" data-start=\"824\" data-end=\"1128\"><span style=\"color: #000000;\"><strong data-start=\"824\" data-end=\"839\">For example<\/strong>, let\u2019s look at the <strong data-start=\"859\" data-end=\"880\">nitride ion (N\u00b3\u207b)<\/strong>. Nitrogen normally has 5 valence electrons (Group 15). However, a 3\u207b charge means it has <strong data-start=\"970\" data-end=\"1002\">gained three extra electrons<\/strong>, making a total of <strong data-start=\"1022\" data-end=\"1045\">8 valence electrons<\/strong>. This is equivalent to the electron configuration of neon (10 electrons in total).<\/span><\/p>\n<p class=\"\" data-start=\"1130\" data-end=\"1288\"><span style=\"color: #000000;\"><strong data-start=\"1130\" data-end=\"1145\">As a result<\/strong>, the Lewis structure of N\u00b3\u207b will show 8 valence electrons around the nitrogen symbol, along with the 3\u207b charge indicated outside the brackets.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">[He]2s<sup>2<\/sup>2p<sup>6<\/sup><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Valence electrons are 8 (2 in 2s and 6 in 2p)<\/span><\/p>\n<figure id=\"attachment_232\" aria-describedby=\"caption-attachment-232\" style=\"width: 712px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Nitride-ion.jpg\" rel=\"attachment wp-att-151\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-232 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Nitride-ion.jpg\" alt=\"lewis dot structure of Nitride ion\" width=\"712\" height=\"581\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Nitride-ion.jpg 712w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-Nitride-ion-300x245.jpg 300w\" sizes=\"auto, (max-width: 712px) 100vw, 712px\" \/><\/a><figcaption id=\"caption-attachment-232\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of Nitride ion<\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Now let us try Lewis dot structure of Sulfide ion ( S<sup>2-<\/sup>).Two negative charges means sulfur atom has gained two electrons so its electronic configuration is with 18 electrons (instead of 16).<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">[Ne]4s<sup>2<\/sup>4p<sup>6<\/sup><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Valence electrons are 8 (2 in 3s and 6 in 3p)<\/span><\/p>\n<figure id=\"attachment_236\" aria-describedby=\"caption-attachment-236\" style=\"width: 742px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-sulfide-ion.jpg\" rel=\"attachment wp-att-153\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-236 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-sulfide-ion.jpg\" alt=\"lewis dot structure of sulfide ion\" width=\"742\" height=\"512\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-sulfide-ion.jpg 742w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-sulfide-ion-300x207.jpg 300w\" sizes=\"auto, (max-width: 742px) 100vw, 742px\" \/><\/a><figcaption id=\"caption-attachment-236\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of sulfide ion<\/strong><\/span><\/figcaption><\/figure>\n<p><span style=\"color: #000000;\">Lewis dot structure will have 4 paired dots around Sulfur atom.For atoms and \u00a0monoatomic ions, step one is sufficient to get the correct Lewis structure.<\/span><\/p>\n<h2><span style=\"color: #000000;\"><strong>Lewis dot structures for Polyatomic ions and molecules :<\/strong><\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">However for molecules and polyatomic ions we need to consider many more factors before drawing a correct Lewis dot structure. Let\u2019s practice step one \u201c<strong>count the total valence electrons<\/strong>\u2019 on molecules and polyatomic ions.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Molecule:<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>SO<sub>2<\/sub>\u00a0\u00a0 (Sulfur dioxide)<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">S is in the 6<sup>th<\/sup> group and O is also in the same group in the periodic table.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Total valence electrons = 6(S) + 2*6(2O) = 6+12=18<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Ion:<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>NO<sub>3<\/sub><sup>&#8211;<\/sup> (nitrate ion)<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Total valence electrons = 5(N) + 3*6(3O) +1 (-1 charge) = 5+18+1=24<\/span><\/p>\n<figure id=\"attachment_240\" aria-describedby=\"caption-attachment-240\" style=\"width: 960px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-of-oxygen-sulfur-and-nitrogen.jpg\" rel=\"attachment wp-att-240\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-240\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-of-oxygen-sulfur-and-nitrogen.jpg\" alt=\"valence electrons of oxygen ,sulfur and nitrogen\" width=\"960\" height=\"560\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-of-oxygen-sulfur-and-nitrogen.jpg 960w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-of-oxygen-sulfur-and-nitrogen-300x175.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/valence-electrons-of-oxygen-sulfur-and-nitrogen-768x448.jpg 768w\" sizes=\"auto, (max-width: 960px) 100vw, 960px\" \/><\/a><figcaption id=\"caption-attachment-240\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Valence electrons of oxygen, sulfur and nitrogen<\/strong><\/span><\/figcaption><\/figure>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\"><strong><span style=\"text-decoration: underline;\">STEP 2\u00a0: MAKE A SKELETON OF THE STRUCTURE<\/span><\/strong><\/span><\/h2>\n<h2 data-start=\"136\" data-end=\"204\"><span style=\"color: #000000;\">How to Choose the Central Atom Using Electronegativity Trends<\/span><\/h2>\n<p class=\"\" data-start=\"206\" data-end=\"381\"><span style=\"color: #000000;\"><strong data-start=\"206\" data-end=\"223\">To begin with<\/strong>, choosing the correct <strong data-start=\"246\" data-end=\"262\">central atom<\/strong> in a Lewis structure requires a solid understanding of <strong data-start=\"318\" data-end=\"339\">electronegativity<\/strong> and its trends across the periodic table.<\/span><\/p>\n<p><span style=\"color: #000000;\"><strong>SELECT\u00a0 LEAST \u00a0ELECTRO-NEGATIVE (EN) \u00a0ATOM \u00a0AS \u00a0THE CENTRAL ATOM AND MAKE A SKELETON OF THE STRUCTURE WITH \u00a0REST \u00a0OF \u00a0THE \u00a0ATOMS \u00a0AROUND IT<\/strong><\/span><\/p>\n<figure id=\"attachment_242\" aria-describedby=\"caption-attachment-242\" style=\"width: 300px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-and-size-of-the-atom.jpg\" rel=\"attachment wp-att-53\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-242 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-and-size-of-the-atom.jpg\" alt=\"EN and size of the atom\" width=\"300\" height=\"241\" \/><\/a><figcaption id=\"caption-attachment-242\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>EN and size of the atom<\/strong><\/span><\/figcaption><\/figure>\n<figure id=\"attachment_243\" aria-describedby=\"caption-attachment-243\" style=\"width: 1443px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-table.jpg\" rel=\"attachment wp-att-149\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-243 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-table.jpg\" alt=\"how to draw Lewis Dot Structure-Electronegativity table \" width=\"1443\" height=\"658\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-table.jpg 1443w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-table-300x137.jpg 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-table-768x350.jpg 768w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/EN-table-1024x467.jpg 1024w\" sizes=\"auto, (max-width: 1443px) 100vw, 1443px\" \/><\/a><figcaption id=\"caption-attachment-243\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Electronegativity table <\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Here is a table that depicts electronegativity trends in the periodic table<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Now let us select\u00a0 least EN atom as the central atom in our molecule <strong>SO<sub>2<\/sub><\/strong>.You can use the periodic table while deciding about it. S is placed below O in the periodic\u00a0 table and hence it is bigger in size and less EN than O.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">SO<sub>2<\/sub>\u00a0\u00a0 S is the central atom because S is less EN then O<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">In the skeleton of the molecule two oxygen atoms making single bonds with S<\/span><\/p>\n<p><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/S02.png\" rel=\"attachment wp-att-162\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/S02.png\" alt=\"Lewis dot structure -S02\" width=\"117\" height=\"60\" \/><\/a><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">NO<sub>3<\/sub><sup>&#8211;<\/sup>\u00a0\u00a0 N is the central atom because N is less EN then O .In the skeleton of the ion three O atoms making three single bonds with central atom N.<\/span><\/p>\n<p><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/NO3-example.png\" rel=\"attachment wp-att-163\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-163 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/NO3-example.png\" alt=\"lewis dot structure NO3 example\" width=\"117\" height=\"115\" \/><\/a><\/span><\/p>\n<h2 data-start=\"139\" data-end=\"198\"><span style=\"color: #000000;\">Key Rules to Remember When Choosing the Central Atom<\/span><\/h2>\n<p class=\"\" data-start=\"200\" data-end=\"275\"><span style=\"color: #000000;\">When drawing a Lewis structure, keep the following important rules in mind:<\/span><\/p>\n<p class=\"\" data-start=\"277\" data-end=\"548\"><span style=\"color: #000000;\"><strong data-start=\"277\" data-end=\"354\">1. The central atom must be capable of forming more than one single bond.<\/strong><\/span><br data-start=\"354\" data-end=\"357\" \/><span style=\"color: #000000;\">In most cases, the central atom needs to bond with multiple surrounding atoms. <strong data-start=\"436\" data-end=\"449\">Therefore<\/strong>, it should have enough valence electrons and available orbitals to accommodate more than one bond.<\/span><\/p>\n<p class=\"\" data-start=\"550\" data-end=\"847\"><span style=\"color: #000000;\"><strong data-start=\"550\" data-end=\"592\">2. Hydrogen and Helium are exceptions.<\/strong><\/span><br data-start=\"592\" data-end=\"595\" \/><span style=\"color: #000000;\">These <strong data-start=\"601\" data-end=\"621\">Group 1 elements<\/strong> can never have more than <strong data-start=\"647\" data-end=\"662\">2 electrons<\/strong> because their electronic configuration includes only the <strong data-start=\"720\" data-end=\"734\">1s orbital<\/strong>.<\/span><br data-start=\"735\" data-end=\"738\" \/><span style=\"color: #000000;\"><strong data-start=\"738\" data-end=\"753\">As a result<\/strong>, they can form <strong data-start=\"769\" data-end=\"786\">only one bond<\/strong> and are <strong data-start=\"795\" data-end=\"825\">never placed at the center<\/strong> of a Lewis structure.<\/span><\/p>\n<p class=\"\" data-start=\"849\" data-end=\"1226\"><span style=\"color: #000000;\"><strong data-start=\"849\" data-end=\"899\">3. Second-period elements have a strict octet.<\/strong><\/span><br data-start=\"899\" data-end=\"902\" \/><span style=\"color: #000000;\">Elements like <strong data-start=\"916\" data-end=\"958\">carbon, nitrogen, oxygen, and fluorine<\/strong> can accommodate a <strong data-start=\"977\" data-end=\"1003\">maximum of 8 electrons<\/strong> in their valence shell.<\/span><br data-start=\"1027\" data-end=\"1030\" \/><span style=\"color: #000000;\"><strong data-start=\"1030\" data-end=\"1064\">This limitation occurs because<\/strong> they lack <strong data-start=\"1075\" data-end=\"1095\">empty d orbitals<\/strong>.<\/span><br data-start=\"1096\" data-end=\"1099\" \/><span style=\"color: #000000;\"><strong data-start=\"1099\" data-end=\"1112\">Therefore<\/strong>, they <strong data-start=\"1119\" data-end=\"1150\">cannot form expanded octets<\/strong>, and you must avoid assigning more than 8 electrons to them in a structure.<\/span><\/p>\n<p class=\"\" data-start=\"1228\" data-end=\"1533\"><span style=\"color: #000000;\"><strong data-start=\"1228\" data-end=\"1290\">4. Third-period and heavier elements can expand the octet.<\/strong><\/span><br data-start=\"1290\" data-end=\"1293\" \/><span style=\"color: #000000;\">Starting from the <strong data-start=\"1311\" data-end=\"1327\">third period<\/strong>, elements have <strong data-start=\"1343\" data-end=\"1367\">available d orbitals<\/strong>, allowing them to hold <strong data-start=\"1391\" data-end=\"1416\">more than 8 electrons<\/strong>.<\/span><br data-start=\"1417\" data-end=\"1420\" \/><span style=\"color: #000000;\"><strong data-start=\"1420\" data-end=\"1436\">Consequently<\/strong>, atoms like <strong data-start=\"1449\" data-end=\"1485\">phosphorus, sulfur, and chlorine<\/strong> can form expanded octet structures when needed.<\/span><\/p>\n<p class=\"\" data-start=\"1535\" data-end=\"1809\"><span style=\"color: #000000;\"><strong data-start=\"1535\" data-end=\"1588\">5. Hydrogen and Fluorine are never central atoms.<\/strong><\/span><br data-start=\"1588\" data-end=\"1591\" \/><span style=\"color: #000000;\">Both require <strong data-start=\"1604\" data-end=\"1625\">only one electron<\/strong> to complete their respective <strong data-start=\"1655\" data-end=\"1669\">duplet (H)<\/strong> and <strong data-start=\"1674\" data-end=\"1687\">octet (F)<\/strong>.<\/span><br data-start=\"1688\" data-end=\"1691\" \/><span style=\"color: #000000;\"><strong data-start=\"1691\" data-end=\"1704\">Therefore<\/strong>, they typically form <strong data-start=\"1726\" data-end=\"1750\">only one single bond<\/strong> and are always placed on the <strong data-start=\"1780\" data-end=\"1791\">outside<\/strong> of the structure.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/HANDF.png\" rel=\"attachment wp-att-164\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-164 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/HANDF.png\" alt=\"H,F - lewis dot structures\" width=\"186\" height=\"85\" \/><\/a><\/span><\/p>\n<h2 style=\"text-align: left;\"><span style=\"text-decoration: underline; color: #000000;\"><strong>STEP 3 : COMPLETE THE OCTET<\/strong>.<\/span><\/h2>\n<p><span style=\"color: #000000;\"><strong>COMPLETE THE OCTET OF THE MOST \u00a0ELECTRONEGATIVE ATOM \u00a0WITH MINIMUM FORMAL CHARGES<\/strong><\/span><\/p>\n<h3 class=\"\" data-start=\"165\" data-end=\"219\"><span style=\"color: #000000;\">Understanding Formal Charge in Lewis Structures<\/span><\/h3>\n<p class=\"\" data-start=\"221\" data-end=\"376\"><span style=\"color: #000000;\">When drawing Lewis structures, it&#8217;s important to determine the <strong data-start=\"284\" data-end=\"301\">formal charge<\/strong> on each atom. This helps assess whether the structure is valid and stable.<\/span><\/p>\n<p class=\"\" data-start=\"378\" data-end=\"589\"><span style=\"color: #000000;\"><strong data-start=\"378\" data-end=\"395\">To begin with<\/strong>, formal charge is the charge assigned to an atom based on the difference between the <strong data-start=\"481\" data-end=\"512\">number of valence electrons<\/strong> it owns in its neutral state and the <strong data-start=\"550\" data-end=\"588\">electrons it uses in the structure<\/strong>.<\/span><\/p>\n<hr class=\"\" data-start=\"591\" data-end=\"594\" \/>\n<h2 data-start=\"596\" data-end=\"625\"><span style=\"color: #000000;\">What Is Formal Charge?<\/span><\/h2>\n<p class=\"\" data-start=\"627\" data-end=\"748\"><span style=\"color: #000000;\"><strong data-start=\"627\" data-end=\"646\">In simple terms<\/strong>, formal charge tells us whether an atom has gained or lost control over its electrons during bonding.<\/span><\/p>\n<p class=\"\" data-start=\"750\" data-end=\"771\"><span style=\"color: #000000;\">We use the formula:<\/span><\/p>\n<p style=\"text-align: left;\"><span class=\"katex-display\" style=\"color: #000000;\"><span class=\"katex\"><span class=\"katex-mathml\">Formal\u00a0Charge\u00a0(FC)=Valence\u00a0electrons\u2212(Bonding\u00a0electrons2)\u2212Lone\u00a0pair\u00a0electrons\\text{Formal Charge (FC)} = \\text{Valence electrons} &#8211; \\left( \\frac{\\text{Bonding electrons}}{2} \\right) &#8211; \\text{Lone pair electrons}<\/span><span class=\"katex-html\" aria-hidden=\"true\"><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Formal\u00a0Charge\u00a0(FC)<\/span><\/span><span class=\"mrel\">=<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Valence\u00a0electrons<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"minner\"><span class=\"mopen delimcenter\"><span class=\"delimsizing size3\">(<\/span><\/span><span class=\"mord\"><span class=\"mfrac\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\">2<span class=\"mord text\">Bonding\u00a0electrons<\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mclose delimcenter\"><span class=\"delimsizing size3\">)<\/span><\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Lone\u00a0pair\u00a0electrons<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n<p class=\"\" data-start=\"913\" data-end=\"1078\"><span style=\"color: #000000;\"><strong data-start=\"913\" data-end=\"930\">Alternatively<\/strong>, since each covalent bond represents one shared electron from the atom, and each lone pair includes two electrons, we can rewrite the formula as:<\/span><\/p>\n<p style=\"text-align: left;\"><span class=\"katex-display\" style=\"color: #000000;\"><span class=\"katex\"><span class=\"katex-mathml\">FC=Group\u00a0Number\u2212Number\u00a0of\u00a0Bonds\u22122\u00d7Number\u00a0of\u00a0Lone\u00a0Pairs\\text{FC} = \\text{Group Number} &#8211; \\text{Number of Bonds} &#8211; 2 \\times \\text{Number of Lone Pairs}<\/span><span class=\"katex-html\" aria-hidden=\"true\"><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">FC<\/span><\/span><span class=\"mrel\">=<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Group\u00a0Number<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Number\u00a0of\u00a0Bonds<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord\">2<\/span><span class=\"mbin\">\u00d7<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Number\u00a0of\u00a0Lone\u00a0Pairs<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n<hr class=\"\" data-start=\"1182\" data-end=\"1185\" \/>\n<h2 data-start=\"1187\" data-end=\"1211\"><span style=\"color: #000000;\">How Does It Work?<\/span><\/h2>\n<p class=\"\" data-start=\"1213\" data-end=\"1237\"><span style=\"color: #000000;\"><strong data-start=\"1213\" data-end=\"1237\">Let\u2019s break it down:<\/strong><\/span><\/p>\n<ul data-start=\"1238\" data-end=\"1438\">\n<li class=\"\" data-start=\"1238\" data-end=\"1324\">\n<p class=\"\" data-start=\"1240\" data-end=\"1324\"><span style=\"color: #000000;\"><strong data-start=\"1240\" data-end=\"1261\">Valence electrons<\/strong> correspond to the atom\u2019s group number in the periodic table.<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"1325\" data-end=\"1392\">\n<p class=\"\" data-start=\"1327\" data-end=\"1392\"><span style=\"color: #000000;\"><strong data-start=\"1327\" data-end=\"1340\">Each bond<\/strong> counts as one electron \u201ccontributed\u201d by the atom.<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"1393\" data-end=\"1438\">\n<p class=\"\" data-start=\"1395\" data-end=\"1438\"><span style=\"color: #000000;\"><strong data-start=\"1395\" data-end=\"1413\">Each lone pair<\/strong> counts as two electrons.<\/span><\/p>\n<\/li>\n<\/ul>\n<p class=\"\" data-start=\"1440\" data-end=\"1662\"><span style=\"color: #000000;\"><strong data-start=\"1440\" data-end=\"1455\">As a result<\/strong>, if an atom ends up with <strong data-start=\"1481\" data-end=\"1499\">more electrons<\/strong> around it than it originally had, it gains a <strong data-start=\"1545\" data-end=\"1571\">formal negative charge<\/strong>.<\/span><br data-start=\"1572\" data-end=\"1575\" \/><span style=\"color: #000000;\">On the other hand, if it has <strong data-start=\"1604\" data-end=\"1623\">fewer electrons<\/strong>, it gets a <strong data-start=\"1635\" data-end=\"1661\">formal positive charge<\/strong>.<\/span><\/p>\n<hr class=\"\" data-start=\"1664\" data-end=\"1667\" \/>\n<h2 data-start=\"1669\" data-end=\"1707\"><span style=\"color: #000000;\">Why Is Formal Charge Important?<\/span><\/h2>\n<p class=\"\" data-start=\"1709\" data-end=\"2011\"><span style=\"color: #000000;\"><strong data-start=\"1709\" data-end=\"1722\">Therefore<\/strong>, calculating formal charge helps determine the <strong data-start=\"1770\" data-end=\"1801\">most stable Lewis structure<\/strong> among several possibilities. A structure where formal charges are minimized\u2014or where negative charges reside on more electronegative atoms\u2014is usually the <strong data-start=\"1956\" data-end=\"1972\">most correct<\/strong> representation of the molecule or ion.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Example:\u00a0 <strong>Oxygen (O),Nitrogen (N),Carbon (C)<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">It has 6 valence electrons so it is very happy with two bonds and two lone pairs in the Lewis dot structures<\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Oxygen-example.png\" rel=\"attachment wp-att-165\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-165 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Oxygen-example.png\" alt=\"Oxygen example: lewis dot structure\" width=\"272\" height=\"83\" \/><\/a><\/span><br \/>\n<span style=\"color: #000000;\"><strong>Valence electrons of O = 6<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 2<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 2<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 6-2-(2*2) =0<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">However if Oxygen has one bond with three lone pairs in Lewis dot structure, then<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Oxygen-example-1.png\" rel=\"attachment wp-att-166\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-166 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Oxygen-example-1.png\" alt=\"Oxygen: 3 lone pairs\" width=\"79\" height=\"98\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of O = 6<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 1<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 3<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 6-2-(2*3) =-1<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Another example:<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>Nitrogen (N)<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">It has 5 valence electrons so it is very happy with three bonds and one lone pair in the Lewis dot structures<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro3.png\" rel=\"attachment wp-att-169\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-169 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro3.png\" alt=\"nitro3 : lewis dot structure\" width=\"86\" height=\"85\" \/><\/a><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro1.png\" rel=\"attachment wp-att-167\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-167 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro1.png\" alt=\"nitro1: lewis dot structure\" width=\"93\" height=\"98\" \/><\/a><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro2.png\" rel=\"attachment wp-att-168\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-168 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro2.png\" alt=\"nitro2- lewis dot structure\" width=\"55\" height=\"72\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of N = 5<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 3<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 1<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 5-3-(2*1) =0<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">However if there are 4 bonds around N which we generally see in many ammonium compounds than it will acquire a formal positive charge<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro3.png\" rel=\"attachment wp-att-169\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-169 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitro3.png\" alt=\"nitro3 : lewis dot structure\" width=\"93\" height=\"92\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of N = 5<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 4<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 0<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 5-4-(2*0) =+1<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Yet another example:<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>Carbon (C)<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">It has 4 valence electrons so it is very happy with four bonds and no lone pairs in the Lewis dot structures.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/carbon1.png\" rel=\"attachment wp-att-170\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-170 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/carbon1.png\" alt=\"carbon1\" width=\"97\" height=\"87\" \/><\/a>\u00a0 \u00a0 \u00a0 \u00a0<a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/carbon2.png\" rel=\"attachment wp-att-171\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-171 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/carbon2.png\" alt=\"carbon2\" width=\"97\" height=\"65\" \/><\/a>\u00a0 \u00a0\u00a0<a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/carbon3.png\" rel=\"attachment wp-att-172\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-172 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/carbon3.png\" alt=\"carbon3\" width=\"100\" height=\"38\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of C = 4<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 4<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 0<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 4-4-(2*0) =0<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">The atoms discussed above are in the second period of the periodic table and hence cannot have more than 8 electrons in the outermost shell (no expanded octet due to lack of d orbitals).<\/span><\/p>\n<figure id=\"attachment_173\" aria-describedby=\"caption-attachment-173\" style=\"width: 688px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/123period.png\" rel=\"attachment wp-att-173\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-173 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/123period.png\" alt=\"how to draw Lewis Dot Structure-expanded octet\" width=\"688\" height=\"119\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/123period.png 688w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/123period-300x52.png 300w\" sizes=\"auto, (max-width: 688px) 100vw, 688px\" \/><\/a><figcaption id=\"caption-attachment-173\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Expanded octet <\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Now, let\u2019s take an element which can have an expanded octet.<\/span><\/p>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">Examples of expanded octet\u00a0<\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>Sulfur\/Sulphur (S)<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">It has 6 valence electrons. So, like oxygen it is also very happy with zero formal charge on it. However, unlike oxygen it has more different combinations to get a zero formal charge. One of the combinations is just like oxygen atom (two bonds and two lone pairs)<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-example.png\" rel=\"attachment wp-att-174\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-174 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-example.png\" alt=\"sulpha example: lewis dot structure\" width=\"87\" height=\"98\" \/><\/a>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-example2.png\" rel=\"attachment wp-att-175\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-example2.png\" alt=\"sulpha example2\" width=\"53\" height=\"98\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of S = 6<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 2<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 2<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 6-2-(2*2) =0<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Second combination is four bonds and one lone pair .Here Sulfur has\u00a010 electrons around it .(expanded octet and extra electrons are accommodated in the empty 3d orbitals of Sulfur).<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-examplesoln1.png\" rel=\"attachment wp-att-176\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-176 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-examplesoln1.png\" alt=\"sulpha examplesoln1\" width=\"97\" height=\"96\" \/><\/a>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-examplesoln1-1.png\" rel=\"attachment wp-att-177\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-177 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-examplesoln1-1.png\" alt=\"sulpha examplesoln2\" width=\"88\" height=\"72\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of S = 6<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 4<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 1<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 6-4-(2*1) = o<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Third combination is 6 bonds and no lone pair . Here Sulfur has\u00a012 electrons around it (expanded octet and extra electrons are accommodated in the empty 3d orbitals of sulfur)<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-final.png\" rel=\"attachment wp-att-178\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-178 size-full aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulpha-final.png\" alt=\"sulpha final lewis dot structure\" width=\"97\" height=\"88\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of S = 6<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 6<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 0<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 6-6-(2*0) =0<\/strong><\/span><\/p>\n<h2 data-start=\"145\" data-end=\"191\"><span style=\"color: #000000;\">Formal Charge Flexibility in Phosphorus<\/span><\/h2>\n<p class=\"\" data-start=\"193\" data-end=\"446\"><span style=\"color: #000000;\">Phosphorus, like nitrogen, has <strong data-start=\"224\" data-end=\"247\">5 valence electrons<\/strong>, so it is also <strong data-start=\"263\" data-end=\"278\">most stable<\/strong> when it carries <strong data-start=\"295\" data-end=\"317\">zero formal charge<\/strong>.<\/span><br data-start=\"318\" data-end=\"321\" \/><span style=\"color: #000000;\"><strong data-start=\"321\" data-end=\"332\">However<\/strong>, unlike nitrogen, phosphorus has <strong data-start=\"366\" data-end=\"396\">more bonding possibilities<\/strong> that allow it to achieve this zero formal charge.<\/span><\/p>\n<p class=\"\" data-start=\"448\" data-end=\"767\"><span style=\"color: #000000;\"><strong data-start=\"448\" data-end=\"464\">For instance<\/strong>, one common and stable arrangement is <strong data-start=\"503\" data-end=\"536\">three bonds and one lone pair<\/strong>, just like nitrogen.<\/span><br data-start=\"557\" data-end=\"560\" \/><span style=\"color: #000000;\"><strong data-start=\"560\" data-end=\"579\">But in addition<\/strong>, phosphorus can also expand its octet (since it is in Period 3), allowing it to form structures with <strong data-start=\"681\" data-end=\"713\">five bonds and no lone pairs<\/strong>, while still maintaining a <strong data-start=\"741\" data-end=\"766\">formal charge of zero<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"769\" data-end=\"948\"><span style=\"color: #000000;\"><strong data-start=\"769\" data-end=\"782\">Therefore<\/strong>, when drawing Lewis structures involving phosphorus, it is essential to consider <strong data-start=\"864\" data-end=\"895\">multiple valid arrangements<\/strong>, especially in molecules like <strong data-start=\"926\" data-end=\"934\">PCl\u2085<\/strong> or <strong data-start=\"938\" data-end=\"947\">H\u2083PO\u2084<\/strong>.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphor1.png\" rel=\"attachment wp-att-182\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-182 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphor1.png\" alt=\"phosphor1\" width=\"54\" height=\"72\" \/><\/a> <a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphor2.png\" rel=\"attachment wp-att-179\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-179 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphor2.png\" alt=\"phosphor2\" width=\"93\" height=\"72\" \/><\/a> <a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphor3.png\" rel=\"attachment wp-att-180\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-180 size-full aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphor3.png\" alt=\"phosphor3: lewis dot structure\" width=\"93\" height=\"94\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of P = 5<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 3<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 1<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 5-3-(2*1) =0<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Second feasible combination to get zero formal charge is five bonds around P . Here phosphorus is with 10 electrons around it (expanded octet and extra electrons are accommodated in the empty 3d orbitals of Phosphorous)<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphorfinal.png\" rel=\"attachment wp-att-183\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-183 size-full aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/phosphorfinal.png\" alt=\"phosphorfinal: lewis dot structure\" width=\"93\" height=\"87\" \/><\/a><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Valence electrons of P = 5<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>No of bonds = 5<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>Lone pairs = 0<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #000000;\"><strong>FC = 5-5-2*0=0<\/strong><\/span><\/p>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">Now let us apply step 3 on our molecule<\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>SO<sub>2<\/sub><\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">From step 2 skeleton of the molecule is<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/S02.png\" rel=\"attachment wp-att-162\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/S02.png\" alt=\"Lewis dot structure -S02\" width=\"107\" height=\"55\" \/><\/a><\/span><\/p>\n<h3 class=\"\" data-start=\"151\" data-end=\"215\"><span style=\"color: #000000;\">Completing the Octet of Oxygen with Minimal Formal Charge<\/span><\/h3>\n<p class=\"\" data-start=\"217\" data-end=\"374\"><span style=\"color: #000000;\">Now that we\u2019ve assigned the basic framework of the Lewis structure, <strong data-start=\"285\" data-end=\"324\">let\u2019s focus on completing the octet<\/strong> of the <strong data-start=\"332\" data-end=\"371\">most electronegative element\u2014oxygen<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"376\" data-end=\"542\"><span style=\"color: #000000;\"><strong data-start=\"376\" data-end=\"397\">As a general rule<\/strong>, when building a Lewis structure, we should <strong data-start=\"442\" data-end=\"511\">always complete the octet of the more electronegative atoms first<\/strong>, and oxygen is no exception.<\/span><\/p>\n<p class=\"\" data-start=\"544\" data-end=\"716\"><span style=\"color: #000000;\"><strong data-start=\"544\" data-end=\"575\">Based on what we&#8217;ve learned<\/strong>, oxygen is <strong data-start=\"587\" data-end=\"602\">most stable<\/strong> when it forms <strong data-start=\"617\" data-end=\"630\">two bonds<\/strong> and holds <strong data-start=\"641\" data-end=\"659\">two lone pairs<\/strong>, which typically results in a <strong data-start=\"690\" data-end=\"715\">formal charge of zero<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"718\" data-end=\"903\"><span style=\"color: #000000;\"><strong data-start=\"718\" data-end=\"731\">Therefore<\/strong>, to satisfy both the octet rule and maintain minimal formal charge, we can <strong data-start=\"807\" data-end=\"829\">confidently assign<\/strong> a <strong data-start=\"832\" data-end=\"866\">double bond and two lone pairs<\/strong> to each oxygen atom in the molecule.<\/span><\/p>\n<p class=\"\" data-start=\"905\" data-end=\"1017\"><span style=\"color: #000000;\"><strong data-start=\"905\" data-end=\"925\">This arrangement<\/strong> keeps the oxygen atoms stable while maintaining the overall charge balance of the molecule.<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Skeleton-of-sulfur-dioxide-molecule-.jpg\" rel=\"attachment wp-att-250\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-250\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Skeleton-of-sulfur-dioxide-molecule-.jpg\" alt=\"Skeleton of sulfur dioxide molecule\" width=\"139\" height=\"116\" \/><\/a><\/span><\/p>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">Let&#8217;s take nitrate ion as the next example.<\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">In the nitrate ion &#8211;\u00a0 NO<sub>3<\/sub><sup>\u2212<\/sup><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">From step 2 skeleton of the molecule is<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/NO3-example.png\" rel=\"attachment wp-att-163\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-163 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/NO3-example.png\" alt=\"lewis dot structure NO3 example\" width=\"115\" height=\"113\" \/><\/a><\/span><\/p>\n<p class=\"\" data-start=\"122\" data-end=\"315\"><span style=\"color: #000000;\">Now that the basic skeleton of the molecule is in place, <strong data-start=\"179\" data-end=\"220\">let\u2019s move on to completing the octet<\/strong> of the <strong data-start=\"228\" data-end=\"264\">most electronegative atom\u2014oxygen<\/strong>\u2014while also aiming for a <strong data-start=\"289\" data-end=\"314\">minimal formal charge<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"317\" data-end=\"518\"><span style=\"color: #000000;\"><strong data-start=\"317\" data-end=\"375\">Since oxygen is usually found at the terminal position<\/strong>, and <strong data-start=\"381\" data-end=\"421\">because it is highly electronegative<\/strong>, it prefers to maintain stability by forming a <strong data-start=\"469\" data-end=\"484\">double bond<\/strong> and holding <strong data-start=\"497\" data-end=\"515\">two lone pairs<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"520\" data-end=\"722\"><span style=\"color: #000000;\"><strong data-start=\"520\" data-end=\"535\">As a result<\/strong>, this arrangement not only satisfies the <strong data-start=\"577\" data-end=\"591\">octet rule<\/strong> but also ensures that the <strong data-start=\"618\" data-end=\"658\">formal charge on oxygen remains zero<\/strong>, making it a safe and reliable choice in most Lewis structures.<\/span><\/p>\n<figure id=\"attachment_185\" aria-describedby=\"caption-attachment-185\" style=\"width: 189px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nightrate.png\" rel=\"attachment wp-att-185\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-185\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nightrate.png\" alt=\"how to draw Lewis Dot Structure - nitrate :invalid structure \" width=\"189\" height=\"175\" \/><\/a><figcaption id=\"caption-attachment-185\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Invalid structure : Central atom nitrogen can not have more than 8 electron<\/strong>s<\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulphur-second-combo-6.png\" rel=\"attachment wp-att-78\">\u00a0<\/a><\/span><\/p>\n<h3 class=\"\" data-start=\"139\" data-end=\"196\"><span style=\"color: #000000;\">Why This Lewis Structure Is Incorrect for Nitrogen<\/span><\/h3>\n<p class=\"\" data-start=\"198\" data-end=\"367\"><span style=\"color: #000000;\">At first glance, the structure might seem acceptable, but upon closer inspection, <strong data-start=\"280\" data-end=\"306\">it violates a key rule<\/strong>: <strong data-start=\"308\" data-end=\"354\">Nitrogen cannot have more than 8 electrons<\/strong> around it.<\/span><\/p>\n<p class=\"\" data-start=\"369\" data-end=\"653\"><span style=\"color: #000000;\"><strong data-start=\"369\" data-end=\"395\">In the structure above<\/strong>, nitrogen is shown forming <strong data-start=\"423\" data-end=\"445\">six covalent bonds<\/strong>, which translates to <strong data-start=\"467\" data-end=\"491\">6 \u00d7 2 = 12 electrons<\/strong>.<\/span><br data-start=\"492\" data-end=\"495\" \/><span style=\"color: #000000;\"><strong data-start=\"495\" data-end=\"506\">Clearly<\/strong>, this exceeds the octet limit for nitrogen, which belongs to the <strong data-start=\"572\" data-end=\"589\">second period<\/strong> and <strong data-start=\"594\" data-end=\"632\">does not have access to d-orbitals<\/strong> to expand its octet.<\/span><\/p>\n<p class=\"\" data-start=\"655\" data-end=\"841\"><span style=\"color: #000000;\"><strong data-start=\"655\" data-end=\"668\">Therefore<\/strong>, we need to <strong data-start=\"681\" data-end=\"705\">adjust the structure<\/strong> to make it chemically valid. Specifically, we should <strong data-start=\"759\" data-end=\"840\">replace two of the double bonds between nitrogen and oxygen with single bonds<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"843\" data-end=\"1180\"><span style=\"color: #000000;\"><strong data-start=\"843\" data-end=\"863\">As a consequence<\/strong>, the two oxygen atoms now forming single bonds with nitrogen <strong data-start=\"925\" data-end=\"966\">require one additional lone pair each<\/strong> to complete their octets.<\/span><br data-start=\"992\" data-end=\"995\" \/><span style=\"color: #000000;\"><strong data-start=\"995\" data-end=\"1023\">In the corrected version<\/strong>, you will observe that both of these oxygen atoms carry <strong data-start=\"1080\" data-end=\"1100\">three lone pairs<\/strong>, which satisfies their octet and ensures formal charges are correctly assigned.<\/span><\/p>\n<figure id=\"attachment_187\" aria-describedby=\"caption-attachment-187\" style=\"width: 171px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitratecorrect.png\" rel=\"attachment wp-att-187\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-187\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitratecorrect.png\" alt=\"how to draw Lewis Dot Structure - nitrate ion : lewis dot structure\" width=\"171\" height=\"170\" \/><\/a><figcaption id=\"caption-attachment-187\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Nitrate ion Lewis dot structure <\/strong><\/span><\/figcaption><\/figure>\n<h2 data-start=\"131\" data-end=\"220\"><span style=\"color: #000000;\">Step 4: Complete the Structure by Adding Remaining Valence Electrons as Lone Pairs<\/span><\/h2>\n<p class=\"\" data-start=\"222\" data-end=\"473\"><span style=\"color: #000000;\">Now that the bonding framework is in place, the <strong data-start=\"270\" data-end=\"284\">final step<\/strong> in drawing a correct Lewis structure is to <strong data-start=\"328\" data-end=\"369\">place the remaining valence electrons<\/strong>\u2014those not yet used in bonds\u2014as <strong data-start=\"401\" data-end=\"415\">lone pairs<\/strong> on the atoms, especially the <strong data-start=\"445\" data-end=\"461\">central atom<\/strong>, if needed.<\/span><\/p>\n<hr class=\"\" data-start=\"475\" data-end=\"478\" \/>\n<h3 class=\"\" data-start=\"480\" data-end=\"535\"><span style=\"color: #000000;\">\ud83d\udd38 Let\u2019s Apply This to an Example: <strong data-start=\"519\" data-end=\"535\">SO\u2082 Molecule<\/strong><\/span><\/h3>\n<ol data-start=\"537\" data-end=\"1228\">\n<li class=\"\" data-start=\"537\" data-end=\"674\">\n<p class=\"\" data-start=\"540\" data-end=\"674\"><span style=\"color: #000000;\"><strong data-start=\"540\" data-end=\"572\">Total valence electrons = 18<\/strong><\/span><br data-start=\"572\" data-end=\"575\" \/><span style=\"color: #000000;\">(This was calculated in Step 1 by adding 6 from sulfur and 6 from each of the two oxygen atoms.)<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"676\" data-end=\"876\">\n<p class=\"\" data-start=\"679\" data-end=\"750\"><span style=\"color: #000000;\"><strong data-start=\"679\" data-end=\"687\">Next<\/strong>, count the number of electrons used so far in the structure.<\/span><\/p>\n<ul data-start=\"754\" data-end=\"876\">\n<li class=\"\" data-start=\"754\" data-end=\"795\">\n<p class=\"\" data-start=\"756\" data-end=\"795\"><span style=\"color: #000000;\">Every bond uses 2 electrons (1 pair).<\/span><\/p>\n<\/li>\n<li class=\"\" data-start=\"799\" data-end=\"876\">\n<p class=\"\" data-start=\"801\" data-end=\"876\"><span style=\"color: #000000;\">Add up the total number of bonding electrons and lone pairs already placed.<\/span><\/p>\n<\/li>\n<\/ul>\n<\/li>\n<li class=\"\" data-start=\"878\" data-end=\"1039\">\n<p class=\"\" data-start=\"881\" data-end=\"965\"><span style=\"color: #000000;\"><strong data-start=\"881\" data-end=\"889\">Then<\/strong>, subtract this number from the total valence electrons (18 in this case).<\/span><\/p>\n<ul data-start=\"969\" data-end=\"1039\">\n<li class=\"\" data-start=\"969\" data-end=\"1039\">\n<p class=\"\" data-start=\"971\" data-end=\"1039\"><span style=\"color: #000000;\">The difference tells you how many electrons are still left to place.<\/span><\/p>\n<\/li>\n<\/ul>\n<\/li>\n<li class=\"\" data-start=\"1041\" data-end=\"1228\">\n<p class=\"\" data-start=\"1044\" data-end=\"1228\"><span style=\"color: #000000;\"><strong data-start=\"1044\" data-end=\"1055\">Finally<\/strong>, assign the remaining electrons as <strong data-start=\"1091\" data-end=\"1105\">lone pairs<\/strong>, starting with the <strong data-start=\"1125\" data-end=\"1157\">outer atoms (usually oxygen)<\/strong>, and place any extra pairs on the <strong data-start=\"1192\" data-end=\"1217\">central atom (sulfur)<\/strong> if needed.<\/span><\/p>\n<\/li>\n<\/ol>\n<p class=\"\" data-start=\"1230\" data-end=\"1420\"><span style=\"color: #000000;\"><strong data-start=\"1230\" data-end=\"1251\">This step ensures<\/strong> that all atoms\u2014especially oxygen and sulfur\u2014achieve stable electron configurations, following the <strong data-start=\"1350\" data-end=\"1364\">octet rule<\/strong> (or expanded octet for sulfur, since it&#8217;s in Period 3).<\/span><\/p>\n<figure id=\"attachment_251\" aria-describedby=\"caption-attachment-251\" style=\"width: 422px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lone-pairs-and-bond-pairs-in-Sulfur-dioxide-molecule.png\" rel=\"attachment wp-att-154\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-251\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lone-pairs-and-bond-pairs-in-Sulfur-dioxide-molecule.png\" alt=\"how to draw Lewis Dot Structure - Lone pairs and bond pairs in Sulfur dioxide molecule\" width=\"422\" height=\"338\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lone-pairs-and-bond-pairs-in-Sulfur-dioxide-molecule.png 773w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lone-pairs-and-bond-pairs-in-Sulfur-dioxide-molecule-300x241.png 300w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/Lone-pairs-and-bond-pairs-in-Sulfur-dioxide-molecule-768x616.png 768w\" sizes=\"auto, (max-width: 422px) 100vw, 422px\" \/><\/a><figcaption id=\"caption-attachment-251\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lone pairs and bond pairs in Sulfur dioxide molecule<\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Number of electron used up to step 3 are<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">4 bond pairs and 4 lone pairs hence total is 4*2(Bond pair) +4*2 (lone pair) =16<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">No of electrons left unused = Total valence electrons \u2013 electrons used in Lewis dot structure<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">= 18-16 =2<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">These left electrons pair is put on the S atom<\/span><\/p>\n<figure id=\"attachment_252\" aria-describedby=\"caption-attachment-252\" style=\"width: 254px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-sulfur-dioxide.jpg\" rel=\"attachment wp-att-252\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-252 size-full\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-of-sulfur-dioxide.jpg\" alt=\"how to draw Lewis Dot Structure - lewis dot structure of SO2\" width=\"254\" height=\"284\" \/><\/a><figcaption id=\"caption-attachment-252\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of sulfur dioxide<\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Now let us calculate the formal charge on each atom in the Lewis dot structure of \u00a0SO2 \u00a0molecule<\/span><\/p>\n<figure id=\"attachment_255\" aria-describedby=\"caption-attachment-255\" style=\"width: 407px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/SO2-formal-charge.jpg\" rel=\"attachment wp-att-255\"><img loading=\"lazy\" decoding=\"async\" class=\" wp-image-255\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/SO2-formal-charge.jpg\" alt=\"SO2 Lewis dot structure \" width=\"407\" height=\"194\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/SO2-formal-charge.jpg 548w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/SO2-formal-charge-300x143.jpg 300w\" sizes=\"auto, (max-width: 407px) 100vw, 407px\" \/><\/a><figcaption id=\"caption-attachment-255\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>SO2 formal charge calculations<\/strong><\/span><\/figcaption><\/figure>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">Now let us check for NO<sub>3<\/sub><sup>&#8211;<\/sup> (nitrate ion)<\/span><\/h2>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Total valence electrons = 24<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Electrons used are as 4 bond pairs and 8 lone pairs =4*2+8*2=24<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Hence all 24 valence electrons are used up .<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Let\u00a0 us calculate formal charge on each atom using the equation<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>FC = Valence electrons \u2013 No\u00a0 of bonds \u2013 2*Lone pairs<\/strong><\/span><\/p>\n<figure id=\"attachment_258\" aria-describedby=\"caption-attachment-258\" style=\"width: 294px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-formal-charge.jpg\" rel=\"attachment wp-att-258\"><img loading=\"lazy\" decoding=\"async\" class=\" wp-image-258\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-formal-charge.jpg\" alt=\"Nitrate ion Lewis dot structure \" width=\"294\" height=\"257\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-formal-charge.jpg 537w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-formal-charge-300x262.jpg 300w\" sizes=\"auto, (max-width: 294px) 100vw, 294px\" \/><\/a><figcaption id=\"caption-attachment-258\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Formal charge on nitrate ion structure<\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>Final Lewis dot structure of NO<sub>3<\/sub><sup>&#8211;<\/sup> (nitrate ion)<\/strong><\/span><\/p>\n<figure id=\"attachment_259\" aria-describedby=\"caption-attachment-259\" style=\"width: 280px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion.jpg\" rel=\"attachment wp-att-259\"><img loading=\"lazy\" decoding=\"async\" class=\" wp-image-259\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion.jpg\" alt=\"NO3- lewis dot structure \" width=\"280\" height=\"282\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion.jpg 428w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-150x150.jpg 150w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-298x300.jpg 298w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitrate-ion-144x144.jpg 144w\" sizes=\"auto, (max-width: 280px) 100vw, 280px\" \/><\/a><figcaption id=\"caption-attachment-259\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Nitrate ion Lewis dot structure<\/strong><\/span><\/figcaption><\/figure>\n<h2 data-start=\"144\" data-end=\"214\"><span style=\"color: #000000;\">Mastering the 4 Key Steps to Draw a Correct Lewis Dot Structure<\/span><\/h2>\n<p class=\"\" data-start=\"216\" data-end=\"433\"><span style=\"color: #000000;\"><strong data-start=\"216\" data-end=\"260\">To accurately draw a Lewis dot structure<\/strong>, you need to follow a set of <strong data-start=\"290\" data-end=\"314\">four essential steps<\/strong>. These steps help ensure your structure is both chemically valid and easy to interpret. Let\u2019s break them down clearly:<\/span><\/p>\n<hr class=\"\" data-start=\"435\" data-end=\"438\" \/>\n<h3 class=\"\" data-start=\"440\" data-end=\"490\"><span style=\"color: #000000;\">Step 1: Count the Total Valence Electrons<\/span><\/h3>\n<p class=\"\" data-start=\"491\" data-end=\"779\"><span style=\"color: #000000;\">First, determine the <strong data-start=\"512\" data-end=\"549\">total number of valence electrons<\/strong> in the molecule or ion.<\/span><br data-start=\"573\" data-end=\"576\" \/><span style=\"color: #000000;\">To do this, simply <strong data-start=\"595\" data-end=\"624\">add the valence electrons<\/strong> from each atom involved.<\/span><br data-start=\"649\" data-end=\"652\" \/><span style=\"color: #000000;\">For ions, don\u2019t forget to <strong data-start=\"678\" data-end=\"707\">add or subtract electrons<\/strong> depending on the charge (add for negative ions, subtract for positive).<\/span><\/p>\n<hr class=\"\" data-start=\"781\" data-end=\"784\" \/>\n<h3 class=\"\" data-start=\"786\" data-end=\"849\"><span style=\"color: #000000;\">Step 2: Choose the Central Atom and Build the Skeleton<\/span><\/h3>\n<p class=\"\" data-start=\"850\" data-end=\"1079\"><span style=\"color: #000000;\">Next, select the <strong data-start=\"867\" data-end=\"883\">central atom<\/strong>\u2014typically the <strong data-start=\"898\" data-end=\"923\">least electronegative<\/strong> element (except hydrogen, which is always terminal).<\/span><br data-start=\"976\" data-end=\"979\" \/><span style=\"color: #000000;\">Then, arrange the surrounding atoms to form the <strong data-start=\"1027\" data-end=\"1055\">basic skeletal structure<\/strong> using <strong data-start=\"1062\" data-end=\"1078\">single bonds<\/strong>.<\/span><\/p>\n<hr class=\"\" data-start=\"1081\" data-end=\"1084\" \/>\n<h3 class=\"\" data-start=\"1086\" data-end=\"1164\"><span style=\"color: #000000;\">Step 3: Complete the Octet of Outer Atoms with Minimum Formal Charges<\/span><\/h3>\n<p class=\"\" data-start=\"1165\" data-end=\"1379\"><span style=\"color: #000000;\">Now, focus on completing the <strong data-start=\"1194\" data-end=\"1243\">octet of the most electronegative atoms first<\/strong> (usually the terminal atoms) using <strong data-start=\"1279\" data-end=\"1293\">lone pairs<\/strong>.<\/span><br data-start=\"1294\" data-end=\"1297\" \/><span style=\"color: #000000;\">At the same time, aim to keep the <strong data-start=\"1331\" data-end=\"1366\">formal charges as close to zero<\/strong> as possible.<\/span><\/p>\n<p class=\"\" data-start=\"1381\" data-end=\"1423\"><span style=\"color: #000000;\">Here\u2019s how to calculate <strong data-start=\"1405\" data-end=\"1422\">formal charge<\/strong>:<\/span><\/p>\n<p><span class=\"katex-display\" style=\"color: #000000;\"><span class=\"katex\"><span class=\"katex-mathml\">Formal\u00a0Charge=Valence\u00a0Electrons\u2212Number\u00a0of\u00a0Bonds\u22122\u00d7Number\u00a0of\u00a0Lone\u00a0Pairs\\text{Formal Charge} = \\text{Valence Electrons} &#8211; \\text{Number of Bonds} &#8211; 2 \\times \\text{Number of Lone Pairs}<\/span><span class=\"katex-html\" aria-hidden=\"true\"><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Formal\u00a0Charge<\/span><\/span><span class=\"mrel\">=<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Valence\u00a0Electrons<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Number\u00a0of\u00a0Bonds<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord\">2<\/span><span class=\"mbin\">\u00d7<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Number\u00a0of\u00a0Lone\u00a0Pairs<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n<p class=\"\" data-start=\"1545\" data-end=\"1565\"><span style=\"color: #000000;\">Or, alternatively:<\/span><\/p>\n<p><span class=\"katex-display\" style=\"color: #000000;\"><span class=\"katex\"><span class=\"katex-mathml\">Formal\u00a0Charge=Group\u00a0Number\u2212Bond\u00a0Pairs\u22122\u00d7Lone\u00a0Pairs\\text{Formal Charge} = \\text{Group Number} &#8211; \\text{Bond Pairs} &#8211; 2 \\times \\text{Lone Pairs}<\/span><span class=\"katex-html\" aria-hidden=\"true\"><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Formal\u00a0Charge<\/span><\/span><span class=\"mrel\">=<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Group\u00a0Number<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Bond\u00a0Pairs<\/span><\/span><span class=\"mbin\">\u2212<\/span><\/span><span class=\"base\"><span class=\"mord\">2<\/span><span class=\"mbin\">\u00d7<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">Lone\u00a0Pairs<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n<p class=\"\" data-start=\"1665\" data-end=\"1789\"><span style=\"color: #000000;\"><strong data-start=\"1665\" data-end=\"1677\">Remember<\/strong>, structures with the <strong data-start=\"1699\" data-end=\"1724\">lowest formal charges<\/strong>, especially on electronegative atoms, are generally more stable.<\/span><\/p>\n<hr class=\"\" data-start=\"1791\" data-end=\"1794\" \/>\n<h3 class=\"\" data-start=\"1796\" data-end=\"1872\"><span style=\"color: #000000;\">Step 4: Place Remaining Electrons as Lone Pairs on the Central Atom<\/span><\/h3>\n<p class=\"\" data-start=\"1873\" data-end=\"2104\"><span style=\"color: #000000;\">Finally, if any valence electrons remain, <strong data-start=\"1915\" data-end=\"1963\">place them as lone pairs on the central atom<\/strong>.<\/span><br data-start=\"1964\" data-end=\"1967\" \/><span style=\"color: #000000;\">This step ensures all electrons are accounted for, and if the central atom is in the third period or beyond, it can <strong data-start=\"2083\" data-end=\"2103\">expand its octet<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"2111\" data-end=\"2264\"><span style=\"color: #000000;\">By mastering these four steps, you\u2019ll be able to construct accurate Lewis dot structures for atoms, ions, molecules, and polyatomic ions with confidence.<\/span><\/p>\n<h2 style=\"text-align: left;\"><span style=\"text-decoration: underline; color: #000000;\">Practice Examples on Lewis Dot Structure:<\/span><\/h2>\n<h3><span style=\"color: #000000;\">NH<sub>4<\/sub><sup>+<\/sup>\u00a0(ammonium ion) Lewis Dot Structure<strong><br \/>\n<\/strong><\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 1<\/span><\/h3>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Total valence electrons = 5(N) + 4*1 (4 H s)-1 (due to one positive charge) = 8<\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 2<\/span><\/h3>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Central atom is N because H can never be the central atom and N is more EN than H. (remember mentioned earlier also)<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Skeleton of NH<sub>4<\/sub><sup>+<\/sup><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitratecorrect-1.png\" rel=\"attachment wp-att-188\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-188 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/nitratecorrect-1.png\" alt=\"ammonium-ion- lewis dot structure\" width=\"133\" height=\"152\" \/><\/a><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/sulphur-second-combo-14.png\" rel=\"attachment wp-att-86\"><br \/>\n<\/a>Step 3\u00a0is already taken care of ,as N has 8 electrons around it\u00a0 and each H is with two electrons on it .<\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 4 :<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Total electrons used are as 4 bond pairs = 4*2 = 8<\/span><\/h3>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Formal charge on N= Valence electrons \u2013 no of bonds \u2013 2*Lone pairs<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">5-4-0 = +1<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Formal charge on H\u00a0\u00a0 = Valence electrons \u2013 no of bonds \u2013 2*Lone pairs<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">= 1-1-0 = 0<\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Final correct Lewis dot structure of ammonium ion is:<\/span><\/h3>\n<figure id=\"attachment_263\" aria-describedby=\"caption-attachment-263\" style=\"width: 210px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/ammonium-ion.jpg\" rel=\"attachment wp-att-263\"><img loading=\"lazy\" decoding=\"async\" class=\" wp-image-263\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/ammonium-ion.jpg\" alt=\"Leiws dot structure of NH4+\" width=\"210\" height=\"202\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/ammonium-ion.jpg 456w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/ammonium-ion-300x289.jpg 300w\" sizes=\"auto, (max-width: 210px) 100vw, 210px\" \/><\/a><figcaption id=\"caption-attachment-263\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of ammonium ion<\/strong><\/span><\/figcaption><\/figure>\n<h2 style=\"text-align: left;\"><span style=\"color: #000000;\">ClO<sub>4<\/sub><sup>&#8211; <\/sup>ion (Perchlorate ion) Lewis dot structure<\/span><\/h2>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 1<\/span><\/h3>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Total valence electrons = 7(Cl) + 4*6 (4 O)+1 (due to one negative\u00a0 charge) = 32<\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 2<\/span><\/h3>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Central atom is Cl because O is more electronegative than Cl (check the periodic table)<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Skeleton of ClO<sub>4<\/sub><sup>&#8211; <\/sup>ion<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-.png\" rel=\"attachment wp-att-189\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-189 aligncenter\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-.png\" alt=\"perchlorate- lewis dot structure\" width=\"117\" height=\"134\" \/><\/a><\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 3<\/span><\/h3>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Complete the octet of oxygen with minimum formal charge .<\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Oxygen being terminal is very happy with a double bond and two lone pairs<\/span><\/p>\n<figure id=\"attachment_191\" aria-describedby=\"caption-attachment-191\" style=\"width: 133px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-22.png\" rel=\"attachment wp-att-191\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-191 \" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-22.png\" alt=\"perchlorate 22\" width=\"133\" height=\"153\" \/><\/a><figcaption id=\"caption-attachment-191\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Invalid Lewis dot structure of perchlorate ion <\/strong><\/span><\/figcaption><\/figure>\n<h3 class=\"\" data-start=\"130\" data-end=\"185\"><span style=\"color: #000000;\">Important Note on Chlorine and Its Bonding Limit<\/span><\/h3>\n<p class=\"\" data-start=\"187\" data-end=\"332\"><span style=\"color: #000000;\"><strong data-start=\"187\" data-end=\"206\">Always remember<\/strong>, chlorine can have a <strong data-start=\"228\" data-end=\"262\">maximum of 7 valence electrons<\/strong>, which limits it to forming <strong data-start=\"291\" data-end=\"308\">up to 7 bonds<\/strong> in a Lewis structure.<\/span><\/p>\n<p class=\"\" data-start=\"334\" data-end=\"576\"><span style=\"color: #000000;\"><strong data-start=\"334\" data-end=\"360\">In the structure above<\/strong>, chlorine is shown forming <strong data-start=\"388\" data-end=\"399\">8 bonds<\/strong>, which exceeds its available valence electrons. <strong data-start=\"448\" data-end=\"463\">As a result<\/strong>, chlorine ends up with a <strong data-start=\"489\" data-end=\"515\">negative formal charge<\/strong>, making the structure less stable and chemically inaccurate.<\/span><\/p>\n<p class=\"\" data-start=\"578\" data-end=\"775\"><span style=\"color: #000000;\"><strong data-start=\"578\" data-end=\"593\">To fix this<\/strong>, we can simply <strong data-start=\"609\" data-end=\"691\">replace one of the double bonds between chlorine and oxygen with a single bond<\/strong>. Then, to complete the <strong data-start=\"715\" data-end=\"743\">octet of the oxygen atom<\/strong>, we add an <strong data-start=\"755\" data-end=\"774\">extra lone pair<\/strong>.<\/span><\/p>\n<p class=\"\" data-start=\"777\" data-end=\"964\"><span style=\"color: #000000;\"><strong data-start=\"777\" data-end=\"802\">This small adjustment<\/strong> brings the formal charge on chlorine back to zero and maintains a valid octet for all atoms involved\u2014resulting in a more <strong data-start=\"924\" data-end=\"963\">stable and accurate Lewis structure<\/strong>.<\/span><\/p>\n<figure id=\"attachment_265\" aria-describedby=\"caption-attachment-265\" style=\"width: 334px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-ion-formal-charges.jpg\" rel=\"attachment wp-att-265\"><img loading=\"lazy\" decoding=\"async\" class=\" wp-image-265\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-ion-formal-charges.jpg\" alt=\"Lewis dot structure of ClO4- ion \" width=\"334\" height=\"237\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-ion-formal-charges.jpg 554w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/perchlorate-ion-formal-charges-300x213.jpg 300w\" sizes=\"auto, (max-width: 334px) 100vw, 334px\" \/><\/a><figcaption id=\"caption-attachment-265\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Formal charge calculations for perchlorate ion<\/strong><\/span><\/figcaption><\/figure>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">(FC = Valence electrons \u2013 no of bonds \u2013 2*Lone pairs)<\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Step 4:<\/span><\/h3>\n<p><span style=\"color: #000000;\"><strong>Electrons used are as 7 bond pairs and 9 lone pairs = 7*2+9*2=32 electrons<\/strong><\/span><\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\">Hence all valence electrons are used and no more electrons are left.<\/span><\/p>\n<h3 style=\"text-align: left;\"><span style=\"color: #000000;\">Final completed correct Lewis dot structure of perchlorate ion \u00a0is<\/span><\/h3>\n<figure id=\"attachment_266\" aria-describedby=\"caption-attachment-266\" style=\"width: 287px\" class=\"wp-caption aligncenter\"><a style=\"color: #000000;\" href=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-ofperchlorate-ion.jpg\" rel=\"attachment wp-att-266\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-266\" src=\"http:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-ofperchlorate-ion.jpg\" alt=\"lewis dot structure of perchlorate ion\" width=\"287\" height=\"304\" srcset=\"https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-ofperchlorate-ion.jpg 361w, https:\/\/www.chemtopper.com\/myblog\/wp-content\/uploads\/2016\/02\/lewis-dot-structure-ofperchlorate-ion-283x300.jpg 283w\" sizes=\"auto, (max-width: 287px) 100vw, 287px\" \/><\/a><figcaption id=\"caption-attachment-266\" class=\"wp-caption-text\"><\/span> <span style=\"color: #000000;\"><strong>Lewis dot structure of perchlorate ion<\/strong><\/span><\/figcaption><\/figure>\n","protected":false},"excerpt":{"rendered":"<p>Understanding the Importance of Lewis Dot Structures To begin with, Lewis dot structure is a classical bonding model that uses only the valence electrons of atoms. It plays a foundational role in chemistry because it connects to many important concepts. For example, Lewis structures are essential for understanding chemical bonding, resonance, valence shell electron pair &hellip;<\/p>\n<p class=\"read-more\"> <a class=\"\" href=\"https:\/\/www.chemtopper.com\/myblog\/how-to-draw-lewis-dot-structure\/\"> <span class=\"screen-reader-text\">How to Draw Lewis Dot Structure<\/span> Read More &raquo;<\/a><\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"categories":[13],"class_list":["post-41","page","type-page","status-publish","hentry","category-ap-chemistry-exam"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.6 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>How to draw Lewis Dot Structure Detailed explanation, examples<\/title>\n<meta name=\"description\" content=\"Lewis Dot Structure. 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