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Chemistry Homework Help => AP Chemistry => Topic started by: Anil on December 29, 2023, 12:41:16 PM

Title: First and Second Order Kinetics Graphs
Post by: Anil on December 29, 2023, 12:41:16 PM
The attachment snipped as in your video shows First order kinetics graph as a decreasing curve and second order Kinetic graph as a increasing curve. Is this correct? Because in class we learnt them as straight lines. We did a Q 45 in Zumdahl and I learnt that st line graph decides the order of reaction and this doubt popped up in my mind? Can you please explain?
Title: Re: First and Second Order Kinetics Graphs
Post by: uma on December 31, 2023, 03:29:44 AM
These curves indicate that reaction is zero order.
In class we have learnt that
[A] vs t is a straight line  with negative slope  for zero order kinetics because integrated rate law for zero order is
[A]t = -kt+[A]0


ln[A] vs t is a straight line with negative slope  for zero order kinetics because integrated rate law for First order is
ln[A]t = -kt+ln[A]0


1/[A] vs t is a straight line for second order kinetics because integrated rate law for second order is
1/[A]t = kt+1/[A]0