AP chemistry Unit 8 (Acids and Bases ) -Excess reactant and limiting reactant & pH

Started by Chandrasekhar, April 17, 2026, 09:04:34 PM

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Chandrasekhar

Hi Mam,

I was wondering how you would approach this problem?Screenshot 2026-04-17 180144.png

uma

HCl + NaOH →  NaCl+ H2O

Step 1: Calculate mmoles of each reactant

mmol of HCl=M×mL=0.25×10.0=2.50 mmol
mmol of NaOH=M×mL=1.5×5.00=7.50 mmol

Step 2: Identify the limiting and excess reactant
Since the reaction is 1 : 1:

HCl = 2.50 mmol
NaOH = 7.50 mmol

So, HCl is the limiting reactant and NaOH is the excess reactant.
Step 3: Use an initial–final table in mmoles
             HCl + NaOH →  NaCl+ H2O
 Initial    2.50   7.50     0      0
  Final     0      5.00     2.50   2.50
After the reaction, 5.00 mmol of NaOH is left in excess.

That means the solution is basic, so  calculate [OH⁻].

Step 4: Calculate the concentration of excess OH⁻

Total volume after mixing: 10.0 mL+5.00 mL=15.0 mL
[OH −]=  15.0 mL /5.00 mmol

           =0.333 M

Step 5: Find pOH and pH

pOH=−log(0.333)=0.48
pH=14.00−0.48=13.52




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