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Chemistry Homework Help => CBSE XI and XII Chemistry => Topic started by: rajive on October 27, 2017, 10:19:41 AM

Title: Chem Bond
Post by: rajive on October 27, 2017, 10:19:41 AM
which of the following has the minimum heat of dissociation of N-->B Bond?
A)[(CH3)3N --> BF3]
B)[(CH3)3N --> B(CH3)F2]
C)[(CH3)3N --> B(CH3)2F]
D)[(CH3)3N --> B(CH3)3]
Title: Re: Chem Bond
Post by: uma on October 30, 2017, 01:42:49 AM
Presence of bulky methyl groups which are electron donating groups make boron less electron deficient and hence weakens the strength of coordinate covalent bond .Bulky groups on N and B create too much of steric repulsion which results in increase in bond length also.Based on the above concept can you answer it now?
Title: Re: Chem Bond
Post by: rajive on December 04, 2017, 10:17:27 AM
Is answer D??