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Chemistry Homework Help => CBSE XI and XII Chemistry => Topic started by: Pranjal Singh on January 11, 2022, 10:19:20 PM

Title: Chemical kinetics
Post by: Pranjal Singh on January 11, 2022, 10:19:20 PM
Here it is
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Title: Re: Chemical kinetics
Post by: chenbeier on January 12, 2022, 03:19:21 AM
The solution is answer 1/3* 10^4 sec. Its not on the list.

The reason its a reaction second order.

B(t) = 1/(k*t + 1/B0)

1,5 m = 1/(10^-4*t+1/3m))

t= 1/3*10^4 sec
Title: Re: Chemical kinetics
Post by: chenbeier on January 12, 2022, 03:29:39 AM
If for compound  A is locked for

Then
A(t) = 1/(k*t + 1/A0)

0,5 m = 1/(10^-4*t+1/2m))

t= 3/2*10^4 sec is the solution. Answer B)
Title: Re: Chemical kinetics
Post by: uma on January 16, 2022, 07:41:59 AM
Quote from: Pranjal Singh on January 11, 2022, 10:19:20 PM
Here it is
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The overall order of the reaction is second order and there is no equation to calculate half life if both reactants are different. However we can calculate using the concept that of pseudo first order and then order with respect to B is first order and this will make half life = ln2/k
k in question is 10^-4 .