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Chemistry Homework Help => CBSE XI and XII Chemistry => Topic started by: rajive on October 27, 2017, 10:08:52 AM

Title: Chem Bonding
Post by: rajive on October 27, 2017, 10:08:52 AM
why does H3SiNCO show back bonding even though it has enough e- to satisfy all valencies.
Title: Re: Chem Bonding
Post by: uma on November 15, 2017, 09:51:54 AM
A structure can become more stable with more delocalization  of lone pairs / or charges .Here lone pair on N can undergo delocalization in the empty d orbitals of Si which results p pi and d Pi back bonding .
Based on it we  have more different questions like
trimethylamine is trigonal pyramidal however trisilylamine is planar?
Title: Re: Chem Bonding
Post by: rajive on December 04, 2017, 09:38:43 AM
Maam understood what u said but won't trisilyamine be 3d instead of planar.(DUE TO ALL THOSE SINGLE BONDS) ??
Title: Re: Chem Bonding
Post by: uma on December 04, 2017, 09:51:54 AM
ipl check the picture ...Can you see double bond character ?
Title: Re: Chem Bonding
Post by: rajive on December 04, 2017, 10:27:02 AM
Let us take Si- . It has 4 groups around it. How can all 4 of them be planar.