When 1 mole A reacts with ½ mole of B2 (A + ½B2 = AB), 100 Kcal heat is liberated and when 1 mole of A reacts with 2 mole of B2( A + 2B2= AB4), 200 Kcal heat is liberated . When 1 mole of A is completely reacted with excess, of B2 to form AB as well as AB4, 140 Kcal heat is liberated calculate the mole of B2 used.
A + 1/2B2 --> AB delta H = 100kcal
A + 2B2 ---> AB4 delta H = 200kcal
Add above two equations
2A + 2.5 B2 ---> AB + AB4 delta H = (100 + 200)kcal =300kcal
For one mole of A
A + 5/4 B2 ---> 1/2 AB + 1/2 AB4 delta H = 300/2 kcal
Hence number moles of B2 used here = 140kcal* 5/4 moles B2/ 150 kcal = 1.16 moles B2