1.1 Counting of atoms

Counting of Macroscopic Particles like apples, socks etc. can be done using small numbers.Macroscopic particles are big and visible so they can be counted easily.

Counting of microscopic particle like atoms and molecules need big numbers.

Counting of Macroscopic or microscopic particles,

Meaning of a pair represents 2 numbers and meaning of a dozen which represents 12 numbers and meaning of Avogadro’s number which represents a mole or  So mole is a counting unit just like a dozen or a pair

Practice Problem

How many water molecules are there ?

In a dozen of water molecules?

Hide- 12 water molecules.

In a pair of water moecules ?

Hide- 2 water molecules

In a mole of water molecules?

Hide-  water molecules

Mole is a counting unit

Definition of a mole

 A mole (mol) is the amount of a substance that contains same number of  particles as there are atoms in exactly 12 g of carbon-12.

So mole is a counting unit just like a dozen or a pair

Number of atoms in 12 g carbon -12 (isotope)

= Avogadro’s number

= 6.022 141 79 × 1023.

Definition of Avogadro’s number

Avogadro’s number is 6.022 141 79 × 1023 number of particles in exactly one mole of any pure substance.

opAvogadro’s Number can be rounded off to 6.022 × 1023.

Avogadro’s number is so large that if all people on the earth start counting atoms in one mole of an element at the rate of 1atom per second, it will take 3 million years for all the atoms to be counted.

Conversion of a mole to number to number of atoms

So, it means 

Now Answer this question

Practice Question -How many atoms are there is 50. moles of Calcium atoms ?

Answer (hidden)

Number of atoms of Ca =

=3.0atoms of Calcium

Practice Question -How many moles are there in atoms of Sodium ?

Answer -Hide

Number of atoms of Sodium =


=10.0 moles of Sodium

Molar Mass

The mass of one mole of a pure substance in grams is called as the molar mass of that substance.

Molar mass

Units of molar mass = grams /mole or  g/mol

By definition a mole of carbon-12 atoms has a mass of exactly 12 g and this is the molar mass of carbon.

Similarly, 1mole of Oxygen atoms has a mass of exactly 16.00 g and it is the molar mass of Oxygen.

You can use periodic table to know the molar masses of the elements.

  Average Atomic masses in grams of an element in the periodic table is the molar mass of the element.

Check for Ag – its average atomic mass is mentioned as 107.87g

So molar mass of Ag is 107.87 g/mol

You can use periodic table to know the molar masses molecules and formula units of ionic compounds.

Let us try to understand the meaning of a formula unit -Mg(NO3)2

has

One formula unit Mg(NO3)2One mol formula unit Mg(NO3)2
No of atomsNumber of atoms x atomic masses in uNo of moles of atomsAtomic masses in grams
1 atom of Mg1 x 24.311 mol of atoms of Mg1 x 24.31
2 atoms of N  2 x 14.012 mol of atoms of N  2 x 14.01
6 atoms of O  6 x 16.006  mol of atoms of O  6 x 16.00
Mass of 1 unit Mg(NO3)2148.33 uMass of 1 mol of  Mg(NO3)2148.33 g/mol

Practice problem -Fill the following table

One molecule of sugar C12H22O11One mole of sugar C12H22O11
No of atomsNumber of atoms x atomic masses in uNo of moles of atomsAtomic masses in grams
      
      
    
Mass of 1 molecule C12H22O11 Mass of 1 mol of  C12H22O11 

Hide answer

One molecule of sugar C12H22O11One mole of sugar C12H22O11
No of atomsNumber of atoms x atomic masses in uNo of moles of atomsAtomic masses in grams
12 atoms of C12 x 12.012 moles of atoms of C12 x 12.0
22 atoms of H  22 x 1.0122 moles of atoms of H  22 x 1.01
11 atoms of O  11 x 16.0011 moles of atoms of O  11 x 16.00
Mass of 1 molecule C12H22O11342.22 uMass of 1 mol of  C12H22O11342.22 g/mol

Conversion of moles/grams

Use this ratio

1mol = molar of the substance

Use periodic table to calculate molar mass as explained above.

Mole to grams

Practice problem

How much mass of water is there in 10 moles of water?

Answer

 = 180 g

Grams to mole

Grams to mole

How many moles are there is 200 g of CaCO3

Answer

= 10 moles

Conversion of moles/grams with molar mass / number of atoms with Avogadro’s Number

From grams to number of atoms or molecules of the substance

 Number of  of the substance

Practice problem

Calculate the number of molecules in 440 grams of CO2

Answer

 Number of  of the substance

Practice problem

Calculate the number of molecules in 440 grams of CO2

Answer

From number of atoms or molecules of the substance to grams of the substance

Practice problem :Calculate mass of   molecules of Sugar molecules.

Answer

Practice problem :Calculate mass of   molecules of Sugar molecules.

Answer


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